Cis–trans isomerism
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SOLVED: The molecule trans-retinal is important in vision.a) Use the PIB model to estimate the wavelength of the photon that would excite trans-retinal into the first excited state. Be sure to take the number of π-electrons into account (hint: each carbon involved in conjugated π-bond contributes one π-electron).b) Experimentally, trans-retinal has an absorbance of 74t at 375 nm. Explain how accurate or inaccurate your value is and explain why it is accurate or inaccurate.
SOLVED: The molecule trans-retinal is important in vision.a) Use the PIB model to estimate the wavelength of the photon that would excite trans-retinal into the first excited state. Be sure to take the number of π-electrons into account (hint: each carbon involved in conjugated π-bond contributes one π-electron).b) Experimentally, trans-retinal has an absorbance of 74t at 375 nm. Explain how accurate or inaccurate your value is and explain why it is accurate or inaccurate.
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